Suppose you have two non-interacting, spin-less particles
in a one-dimensional potential, each in one of two single-particle, orthonormal
eigenstates ψ1(x) and ψ2(x)
of that potential. Now suppose you measure the position of one of the
particles in an ensemble of identically prepared experiments. What is the
expectation value of position if the particles are
(a) distinguishable particles,
(b) identical bosons,
(c) identical fermions?
In
any one of these cases, if there is more than one answer to the question,
provide all of them.
(a) If the spin of the electron were (3/2)ħ,what spectroscopic terms
2S+1LJ would exist for the electron configuration 2p, 3p?
(b)
If the spin of the electron were (3/2)ħ,what spectroscopic terms
2S+1LJ
would exist for the electron configuration (3p)2?
Consider N >> 1 non-interacting
spin-½ particles with mass M confined to a cubical box of volume V.
(a) Derive an expression for the Fermi energy.
(b) Make some numerical estimates, assuming in each case that the particles in
question are non-interacting, for the Fermi energy of
(i) electrons in a typical metal,
(ii) nucleons in a large nucleus,
(iii) 3He atoms in liquid 3He, which has an atomic volume
of about 0.05 nm3 per atom.
Two identical spin zero bosons are placed in a one-dimensional infinite square
well, U(x) = ∞, x < 0 and x > a, U(x) = 0, 0 < x <
a. The bosons interact weakly with one another via the potential energy
function U(x1,x2) = -aU0δ(x1 - x2),
where U0 is a constant with the dimensions of energy.
(a) First,
ignoring the interaction between the particles, find the ground state and first
excited state wave functions and the associated energies.
(b) Use first-order perturbation theory to estimate the effect of the
particle-particle interaction on the energies of the ground state and the first
excited state.
Useful integrals:
∫0
π sin4(x) dx = 3π/8
∫0 π sin2(x)sin2(2x) dx = π/4