The expression for the mean value of an observable A
in the normalized state |Ψ> is <A> = <Ψ|A|Ψ>.
If |Ψ>
is not normalized then < A> = <Ψ|A|Ψ>/<Ψ|Ψ>.
<x> = <Ψ|X|Ψ> = ∫
d3r <Ψ|r><r|X|Ψ> = ∫ d3r Ψ*(r)
x Ψ(r).
<px> = <Ψ|Px|Ψ> = ∫
d3r <Ψ|r><r|Px|Ψ> = ∫ d3r
Ψ*(r) (ħ/i)∂Ψ(r)/∂x.
The root mean square deviation ΔA characterizes the dispersion of the measurement around <A>.
ΔA = (<(A - <A>)2>)1/2.
ΔA = (<(A - <A>)2>)1/2
= (<Ψ|(A - <A>)2|Ψ>)1/2
= (<Ψ|A2|Ψ> - 2<A><Ψ|A|Ψ> + <A>2<Ψ|Ψ>)1/2
= (<A2> - 2<A><A> + <A>2)1/2
= (<A2> - <A>2)1/2.
ΔA is a measure of the spread that one should expect in
the result of a measurement of the observable A.
Problem:
Assume the wave function of a particle is Ψ(x) = N exp(ip0x/ħ)/(x2
+ a2)1/2.
Here a and p0 are real constants and N is a
normalization constant.
(a) Find N so that ψ(x) is normalized.
(b) If the position of the particle is measured, what is the probability of
finding the particle between -a/√3 and +a/√3?
(c) Calculate the mean value of the momentum of the particle.
(b) Let P denote the probability of finding the particle between
-a/√3 and +a/√3.
Let y = a/√3.
P = ∫-y+y |Ψ(x)|2 dx = (a/π)∫-y+ydx/(x2
+ a2) = (1/π)tan-1(x/a)|-y+y
= (1/π)[tan-1(1/√3) - tan-1(-1/√3)]
= (1/π)[π/6 + π/6] = 1/3.
(c) Let <P> denote the mean value of the momentum of the particle.
<P> = ∫-∞+∞Ψ*(x) ((ħ/i)∂/∂x) Ψ(x) dx
= (a/π)∫-∞+∞exp(-ip0x/ħ)/(x2
+ a2)1/2 (ħ/i)[(ip0/ħ)exp(ip0x/ħ)/(x2
+ a2)1/2 - x exp(-ip0x/ħ)/(x2
+ a2)3/2]
= (a/π)p0∫-∞+∞dx/(x2
+ a2) - (a/π)(ħ/i)∫-∞+∞
xdx/(x2
+ a2)2 = p0.
(π/a)
0, odd function
Proof:
Let |Ψ> be any state vector and let A1
= A
- <A>I and B1 = B - <B>I.
Let |Φ>
= A1|Ψ> + ixB1|Ψ> with x an arbitrary real
number.
Then <Φ| = <Ψ|A1 - ix<Ψ|B1.
<Φ|Φ> = <Ψ|A12|Ψ>
+ x2<Ψ|B12|Ψ> - ix<Ψ|B1A1|Ψ>
+ ix<Ψ|A1B1|Ψ>
= <A12> + x2<B12>
+ x<Ψ|i[A1,B1]Ψ>
= (ΔA)2 + x2(ΔB)2
+ x<i[A,B]>
for all x. But <Φ|Φ> ≥ 0.
Therefore = (ΔA)2
+ x2(ΔB)2
+ x<i[A,B]> ≥ 0 for all x.
For this to be true we either need that the quadratic equation y = ax2
+ bx + c
either has no zeros, or is equal to zero for only one value of x. (The equation
describes a parabola. The vertex of the parabola can either touch the x-axis or
must lie above the x-axis.) To find a root we set x = (b ± (b2
- 4ac)1/2)/(2a).
If b2 < 4ac the equation has no roots.
If b2 = 4ac or x = -b/2a the equation is zero.
We therefore need b2 < 4ac .
Therefore |<i[A,B]>|2 ≤
4(ΔA)2(ΔB)2.