In many treatments in current journals you find authors using the interaction
picture. Assume the Hamiltonian of an arbitrary system is H0(t),
and the corresponding evolution operator is U0(t,t0).
We have
(iħ∂/∂t)U0(t,t0) = H0(t)U0(t,t0),
U0(t0,t0) = I.
Now assume that the system is perturbed in such a way that the Hamiltonian becomes
H(t) = H0(t) + W(t).
For such a system the state vector in the interaction picture, |ΨI(t)>
is defined from the state vector in the Schroedinger picture through
|ΨI(t)>
= U0(t,t0)|ΨS(t)>.
How does |ΨI(t)>
evolve?
iħ∂|ΨI(t)>/∂t = iħ∂/∂t(U0(t,t0)|ΨS(t)>)
= iħ[∂/∂t(U0(t,t0)]|ΨS(t)>)
+ iħU0(t,t0)[∂/∂t(|ΨS(t)>]
= -U0(t,t0)H0s(t)|ΨS(t)>)
+ U0(t,t0)Hs(t)|ΨS(t)>.
Here we used
iħ∂/∂t U0(t,t0) = H0(t)U0(t,t0),
-iħ∂/∂t U0(t,t0) = U0(t,t0)H0(t).
We now can write
iħ∂|ΨI(t)>/∂t = -U0H0S(t)U0U0|ΨS(t)>
+ U0Hs(t)U0U0|ΨS(t)>
= -H0I(t)ΨI(t)> + (H0I(t) + WI(t))|ΨI(t)>
= WI(t))|ΨI(t)>.
Therefore
iħ∂|ΨI(t)>/∂t = WI(t))|ΨI(t)>.
We can rewrite this differential equation in the form of an integral equation.
d|ΨI(t)> = (iħ)-1WI(t))|ΨI(t)>dt.
∫t0t d|ΨI(t)> = (iħ)-1∫t0t
WI(t')|ΨI(t')>dt'.
|ΨI(t)> = |ΨI(t0)> + (iħ)-1∫t0t
WI(t')|ΨI(t')>dt'
ŻŻ_______________________________ŻŻ
This integral equation can be solved by iteration.
The ket |ΨI(t)> can be
expanded in a power series of the form
|ΨI(t)> = {I + (iħ)-1∫t0t
dt'WI(t') + (iħ)-2∫t0t
dt'WI(t') ∫t0t' dt''WI(t'')
+ ... }|Ψ0(t)>.
The interaction picture assigns part of the time dependence to the state vectors, and
part to the operators. Following the method used to derive the equation for the evolution
of the operators in the Heisenberg picture, we can derive the equation for the evolution
of operators in the interaction picture.
dAI/dt = (∂AS/∂t)I+ (iħ)-1[AI,H0I].
When do we use the interaction picture?
The interaction picture is often used when H0S is time-independent
and WS(t) is a small correction to H0S.
Assume that
the problem governed by H0S is already solved, either exactly, or in
some approximation.
Assume WS(t) = 0 for t < 0.
Then |ΨI(0)> = |ΨS(0)>.
Neglecting higher order terms we have
|ΨI(t)> = |ΨI(t0)> + (iħ)-1∫t0t
WI(t')|ΨI(0>dt'
with WI(t) = exp(iH0t/ħ) WS(t) exp(-iH0t/ħ).
Let {|n>} be an orthonormal eigenbasis of H0 and let the
system be in the eigenstate |m> at t = 0, i.e. |ΨI(0)> = |m>.
We have H0|m> = Em|m>,
The probability P(Ek,t) of finding the system in the eigenstate |k>
of H0 at time t, i.e. the probability of measuring the
eigenvalue Ek, is |<k|ΨI(t)>|2..
(The predictions of quantum mechanics are independent of the representation.)
<k|ΨI(t)> = <k|m> + (iħ)-1∫0t
<k|WI(t')|m>dt'
= <k|m> + (iħ)-1∫0t
exp(i(Ek - Em)t/ħ) <k|WS(t')|m>dt'.
With <k|m> = 0 we have
P(Ek,t) = (1/ħ2)|∫0t exp(i(Ek
- Em)t/ħ) <k|WS(t')|m>dt'|2.
This is the result of first order time dependent perturbation theory. P(Ek,t) is the transition probability.
If WS(t) is independent of time, i.e. if a constant
small term is added to the Hamiltonian at t = 0 then
P(Ek,t) = (1/ħ2)|<k|WS|m>|2|
(exp(i(Ek - Em)t/ħ - 1)/(i(Ek - Em)/ħ)|2
= (1/ħ2)|<k|WS|m>|2| (exp(-iEmt/ħ
- exp(-iEkt/ħ)/(i(Ek - Em)/ħ)|2
= (|<k|WS|m>|2/(Ek - Em)2)
(2 sin(ωkmt/2))2
= (|<k|WS|m>|2/(Ek - Em)2) 4
sin2(ωkmt/2).
Here ωkm = (Ek - Em)/ħ and we have used |eiθ - eiφ| = 2sin((θ - φ)/2).
Problem:
Consider a one-dimensional, infinitely deep well. Let U(x) = 0, for
0 < x < a, and U(x) = ∞ everywhere else. The eigenstates of H0 = p2/(2m) +
U(x) are Φn(x) = (2/a)1/2sin(nπx/a)
with eigenvalues En = n2π2ħ2/(2ma2).
Assume that at t = 0 you put a coin on the bottom of the well.
W(x) = W0, a/4 < x < 3a/4 for t > 0, W(x) = 0 everywhere
else, H = H0 + W.
If at t = 0 the system is in the state Φ3(x),
what is the probability of finding it in Φ1(x)
at time t?
Solution: