
Consider a particle of mass m moving in a potential
.
The force on the particle is given by
.
The motion of the classical particle is governed by Newtons second law
.
The general solution to this equation is
,
with
.
We have
.
.
The total energy is independent of time, we have a conservative system.
To make the transition to Quantum Mechanics we express E in terms of p and x and then replace the classical quantities p and x by their corresponding quantum mechanical operators P and X.
.
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Define
,
where
.
have the same eigenstates,
their eigenvalues differ by a factor of
.
do not commute.
.
Let us define some new operators and investigate their properties. Define
.
Then
Note that a and aT do not commute.
.
Now we study the product operator
.
Similarly,
.
We may therefore write
.
Define the number operator N=aTa. Then
.
and N have common eigenstates, finding the
eigenstates of N is equivalent to finding the eigenstates of
.
The operator N does not commute
with a and aT.
.
.
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We will now study some of the properties of the eigenstates of N and therefore
the eigenstates of
.
(a) The eigenvalues of N are positive.
| |||
(b) If |fn> is an eigenstate of N
with eigenvalue
| |||
(c) If |fn> is an eigenstate of N
with eigenvalue
| |||
(d) The eigenvalues of N are the non negative integers.
| |||
(e) The ground state of
|
The eigenvectors {|fn> } of
are a basis for the state space Ex
of a particle in a one dimensional problem. The |fn>
are orthogonal since all eigenvalues are not degenerate. We now want to choose a normalized
set {|fn> }.
| Assume |f0> is normalized, <f0|f0>=1. The normalized vector |f1> is |f1>=c1aT|f0>. If <f1|f1>=1, then |c1|2 <f0|aaT|f0>=|c1|2 <f0|aTa+1|f0>=|c1|2 =1. Therefore |f1>=aT|f0>. | |
| The normalized vector |fn> is |fn>=cnaT|fn-1>. | |
| If <fn|fn>=1,
then |cn|2 <fn-1|aaT|fn-1>=|cn|2<fn-1|aTa+1|fn-1>=n|cn|2
=1. Therefore |fn>=
The set
Let {|fn>} denote this orthonormal
eigenbasis of the operator
| |
| The results of operating with a or aT on |fn> are given by
The matrices representing a and aT in the {|fn>} basis therefore are |
.
The order of the basis vectors is
.
| In terms of a and aT the observables X an P are given by |
.
The matrices representing X and P therefore are

.
X and P are Hermitian operators.