Problem 1:
The Hamiltonian operator for a two state system is given by
H = a(|1><1|-|2><2|+|1><2|+|2><1|),
where a is a number with the dimensions of energy.
(a) Find the
eigenvalues of H and the corresponding eigenkets |ψ1> and
|ψ2> (as linear combinations of |1> and |2>).
(b) A unitary transformation maps the {|1>, |2>} basis onto the {|ψ1>,
|ψ2>}
basis. We have U|i> = |ψi>. Write down
the matrix of U and the matrix of U† in the {|1>, |2>}
basis.
Let P and Q be two linear operators and
let [P,Q] = -iħ. Find
(a) [Q,P],
(b) [Q,Pn],
(c) [P,Qn] .
Suppose |i> and |j> are eigenkets of some
Hermitian operator A. Under what conditions can we conclude that |i> + |j>
is also an eigenket? Justify your answer.
Using the rules of bra-ket algebra, prove or
evaluate the following:
(a) tr(XY) = tr(YX), where X and Y are
operators.
(b) (XY)† = Y†X†
(c) exp(i f(A)) = ?, in ket-bra form, where A is a Hermitian operator
whose eigenvalues are known.
(d) ∑a'ψ*a'(r')ψa'(r''),
where ψa'(r') = <r'|a'>.
Assume {|1>, |2>, |3>, ... , |n>} forms an orthonormal basis for the
vector space V. Let Ωij be the matrix
elements of the Hermitian operator Ω in this basis.
Assume that the set {|1>, |2>, |3>, ... , |n>} is not an
eigenbasis of Ω, but that the unitary transformation
U|i> = |ωi>
changes this basis to the eigenbasis {|ω1>, |ω2>, |ω3>,
... , |ωn>} of Ω.
We have Ω|ωi> = ωi|ωi>.
In
this basis the matrix of Ω is diagonal.
Let Uij
denote the matrix elements of the unitary operator in the {|1>, |2>, |3>, ...
, |n>} basis, Uij = <i|U|j> = <i|ωi>.
The
matrix elements of Ω in the {|ωi>}
basis are the same as the matrix elements of U†ΩU
in the {|i>} basis. The matrix of U†ΩU
in the {|i>} basis is diagonal, <i|U†ΩU|j> = 0
if i ≠ j.
<i|U†ΩU|j> = ∑kl<i|U†|k><k|Ω|l><l|U|j>
= ∑klU†ikΩklUlj.
We can therefore diagonalize the matrix
Ω by
multiplying it from the left by U† and from the right by
U.
Consider the matrix
in the {|i>}
basis.
(a) Is this matrix Hermitian?
(b) Find its eigenvalues ωi and eigenvectors |ωi>.
(c) Find the matrix of U in the {|i>} basis.
(d) Find the matrix of U† in the {|i>} basis. (U
changes {|i>} into {|ωi>}.)
(e) Verify that UU† = U†U = I.
(f) Verify that the matrix U†ΩU in
the {|i>} basis is diagonal.